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Removal of Evans Blue and Yellow thiazole dyes from aqueous solution by Mg-Al-CO3 Layered Double Hydroxides as anion-exchanger

Mohamed Bouraada, Hassiba Bessaha, Louis Charles de Ménorval

Abstract


Mg-Al-CO3 Layered double hydroxide (LDH) was prepared by co-precipitation method at constant pH, and subsequently used to remove Evans Blue (EB) and Yellow thiazole (YT) dyes from aqueous solutions.
The obtained material was characterized by powder X-ray diffraction (PXRD), Fourier transform infrared spectroscopy (FTIR), thermal analysis and BET. The kinetic and equilibrium aspects of sorption of the anionic dyes from aqueous solution by Mg-Al-CO3 were investigated in batch mode. The sorption kinetic data were found to be consistent with the pseudo-second-order model. Data for YT and EB sorption by Mg-Al-CO3 were fitted better by the Langmuir equation than by the Freundlich equation based on the determination coefficient values R2. The maximum adsorption capacities of 222.2 mgg-1 for Yellow thiazole and 107.5 mgg-1 for Evans blue. The thermodynamic parameters including Gibbs free energy (ï„ G°), standard enthalpy change (ï„ H°), and standard entropy change (ï„ S°) for the process were calculated. The negative ï„ G° value indicates the spontaneity of the removal process.


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DOI: http://dx.doi.org/10.13171/mjc.3.3.2014.01.06.18

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