Graphical Abstract

Removal of sodium salicylate from aqueous solution using spruce wood sawdust as an eco-friendly adsorbent

Nouh Aarab, Abdelilah Essekri, Mohamed Ait Haki, Hassan Kabli, Habiba Eljazouli, Maria Elamine, Rajae Lakhmiri, Abdallah Albourine

Abstract


This study reports the application of Spruce wood sawdust as a low-cost and eco-friendly adsorbent for the removal of sodium salicylate from aqueous solutions. The effects of physicochemical parameters on the sodium salicylate adsorption process such as initial pH, temperature, solid/liquid ratio, initial concentration, contact time, and ionic strength were investigated. The optimum adsorption conditions were found as: equilibrium time = 3h, adsorbent dosage = 0.5 g/L, pH= 6.5, initial sodium salicylate concentration = 10 mg/L and temperature = 25°C. The kinetic study shows that the pseudo-second-order model is suitable to describe the adsorption process. The adsorption isotherm models (Langmuir, Freundlich, Temkin and generalized) were tested to understand the adsorption mechanism of sodium salicylate onto wood sawdust surface. The adsorption of sodium salicylate follows the Langmuir isotherm model. The maximum monolayer uptake capacity was found to be 99.01 mg/g. In addition, the temperature seems to have no noticeable effect on the adsorption of sodium salicylate. Finally, the thermodynamic parameters indicate that the adsorption is spontaneous (ΔG°˂ 0) and exothermic (ΔH°=-5.081 kJ/mol) in nature. Overall, Spruce wood sawdust can be used as a cost-effective and eco-friendly adsorbent for wastewater treatment applications.


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References


- M. Jureczko, J. Kalka, Cytostatic pharmaceuticals as water contaminants, Eur J Pharmacol, 2020, 866, 172816.

- N. Serpone, Y. M. Artemev, V. K. Ryabchuk, A. V. Emeline, S. Horikoshi, Light-driven advanced oxidation processes in the disposal of emerging pharmaceutical contaminants in aqueous media: A brief review, Curr Opin Green Sustain Chem, 2017, 6, 18–33.

- D. Kanakaraju, B. D. Glass, M. Oelgemöller, Advanced oxidation process-mediated removal of pharmaceuticals from water: A review, J Environ Manage, 2018, 219, 189–207.

- R. G. Combarros, I. Rosas, A. G. Lavín, M. Rendueles, M. Díaz, Influence of Biofilm on Activated Carbon on the Adsorption and Biodegradation of Salicylic Acid in Wastewater, Water Air Soil Pollut, 2014, 225, 1858.

- S. Dobaradaran, R. N. Nodehi, K. Yaghmaeian, J. Jaafari, M. H. Niari, A. K. Bharti, S. Agarwal, V. K. Gupta, A. Azari, N. Shariatifar, Catalytic decomposition of 2-chlorophenol using an ultrasonic-assisted Fe3O4–TiO2@MWCNT system: Influence factors, pathway and mechanism study, J Colloid Interface Sci, 2018, 512, 172–189.

- R. Saravanan, E. Sacari, F. Gracia, M. M. Khan, E. Mosquera, V. K. Gupta, Conducting PANI stimulated ZnO system for visible light photocatalytic degradation of coloured dyes, J Mol Liq, 2016, 221, 1029–1033.

- S. Rajendran, M. M. Khan, F. Gracia, J. Qin, V. K. Gupta, S. Arumainathan, Ce3+-ion-induced visible-light photocatalytic degradation and electrochemical activity of ZnO/CeO2 nanocomposite, Sci Rep, 2016, 6, 31641.

- R. Saravanan, E. Thirumal, V. K. Gupta, V. Narayanan, A. Stephen, The photocatalytic activity of ZnO prepared by simple thermal decomposition method at various temperatures, J Mol Liq, 2013, 177, 394–401.

- V. K. Gupta, N. Atar, M. L. Yola, Z. Üstündağ, L. Uzun, A novel magnetic Fe@Au core–shell nanoparticles anchored graphene oxide recyclable nanocatalyst for the reduction of nitrophenol compounds, Water Res, 2014, 48, 210–217.

- I. Ali, V. K. Gupta, T. A. Khan, M. Asim, Removal of Arsenate from Aqueous Solution by Electro- Coagulation Method Using Al-Fe Electrodes, Int J Electrochem Sci, 2012, 7, 1898 - 1907.

- N. Aarab, M. Laabd, H. Eljazouli, R. Lakhmiri, H. Kabli, A. Albourine, Experimental and DFT studies of the removal of pharmaceutical metronidazole from water using polypyrrole, Int J Ind Chem, 2019, 10, 269–279.

- A. Azari, M. Gholami, Z. Torkshavand, A. R. Yari, E. Ahmadi, B. Kakavandi, Evaluation of basic violet 16 adsorption from aqueous solution by magnetic zero valent iron-activated carbon nanocomposite using response surface method: Isotherm and kinetic studies, J Mazandaran Univ Med Sci, 2015, 25, 333–347.

- A. Azari, M. Salari, M. H. Dehghani, M. Alimohammadi, H. Ghaffari, K. Sharafi, N. Shariatifar, M. Baziar, Efficiency of Magnitized Graphene Oxide Nanoparticles in Removal of 2,4-Dichlorophenol from Aqueous Solution, J Mazandaran Univ Med Sci, 2017, 26, 265–281.

- A. Karami, K. Karimyan, R. Davoodi, M. Karimaei, K. Sharafie, S. Rahimi, T. Khosravi, M. Miri, H. Sharafi, A. Azari, Application of response surface methodology for statistical analysis, modeling, and optimization of malachite green removal from aqueous solutions by manganese-modified pumice adsorbent, Desalination Water Treat, 2017, 89, 150–161.

- A. E. Burakov, E. V. Galunin, I. V. Burakova, A. E. Kucherova, S. Agarwal, A. G. Tkachev, V. K. Gupta, Adsorption of heavy metals on conventional and nanostructured materials for wastewater treatment purposes: A review, Ecotoxicol Environ Saf, 2018, 148, 702–712.

- T. A. Saleh, V. K. Gupta, Processing methods, characteristics and adsorption behavior of tire derived carbons: A review, Adv Colloid Interface Sci, 2014, 211, 93–101.

- V. K. Gupta, T. A. Saleh, Sorption of pollutants by porous carbon, carbon nanotubes and fullerene- An overview, Environ Sci Pollut Res, 2013, 20, 2828–2843.

- S. K. Ghosh, Waste Management and Resource Efficiency: Proceedings of 6th IconSWM 2016, Springer Singapore: Singapore, 2019. doi:10.1007/978-981-10-7290-1.

- Suhas, V. K. Gupta, P. J. M. Carrott, R. Singh, M. Chaudhary, S. Kushwaha, Cellulose: A review as natural, modified and activated carbon adsorbent, Bioresour Technol, 2016, 216, 1066–1076.

- A. Sharma, S. A. Chaudhry, Adsorption of Pharmaceutical Pollutants Using Lignocellulosic Materials, Green Materials for Wastewater Treatment, 2020, 277–289. doi:10.1007/978-3-030-17724-9_12.

- R. Chakraborty, R. Verma, A. Asthana, S. S. Vidya, A. K. Singh, Adsorption of hazardous chromium (VI) ions from aqueous solutions using modified sawdust: kinetics, isotherm and thermodynamic modelling, Int J Environ Anal Chem, 2019, 1–18.

- F. Nekouei, S. Nekouei, I. Tyagi, V. K. Gupta, Kinetic, thermodynamic and isotherm studies for acid blue 129 removal from liquids using copper oxide nanoparticle-modified activated carbon as a novel adsorbent, J Mol Liq, 2015, 201, 124–133.

- M. Laabd, H. Chafai, N. Aarab, A. El Jaouhari, M. Bazzaoui, H. Kabli, H. Eljazouli, A. Albourine, Polyaniline films for efficient removal of aromatic acids from water, Environ Chem Lett, 2016, 14, 395–400.

- N. Mohammadi, H. Khani, V. K. Gupta, E. Amereh, S. Agarwal, Adsorption process of methyl orange dye onto mesoporous carbon material–kinetic and thermodynamic studies, J Colloid Interface Sci, 2011, 362, 457–462.

- M. El Ouardi, M. Laabd, H. Abou Oualid, Y. Brahmi, A. Abaamrane, A. Elouahli, A. Ait Addi, A. Laknifli, Efficient removal of p-nitrophenol from water using montmorillonite clay: insights into the adsorption mechanism, process optimization, and regeneration, Environ Sci Pollut Res, 2019, 26, 19615–19631.

- A. Mesdaghinia, A. Azari, R. N. Nodehi, K. Yaghmaeian, A. K. Bharti, S. Agarwal, V. K. Gupta, K. Sharafi, Removal of phthalate esters (PAEs) by zeolite/Fe3O4: Investigation on the magnetic adsorption separation, catalytic degradation and toxicity bioassay, J Mol Liq, 2017, 233, 378–390.

- Z. Berizi, S. Y. Hashemi, M. Hadi, A. Azari, A. H. Mahvi, The study of non-linear kinetics and adsorption isotherm models for Acid Red 18 from aqueous solutions by magnetite nanoparticles and magnetite nanoparticles modified by sodium alginate, Water Sci Technol, 2016, 74, 1235–1242.

- M. Yegane Badi, A. Azari, H. Pasalari, A. Esrafili, M. Farzadkia, Modification of activated carbon with magnetic Fe3O4 nanoparticle composite for removal of ceftriaxone from aquatic solutions, J Mol Liq, 2018, 261, 146–154.

- M. Laabd, A. El Jaouhari, M. Bazzaoui, A. Albourine, H. El Jazouli, Adsorption of Benzene-Polycarboxylic Acids on the Electrosynthesized Polyaniline Films: Experimental and DFT Calculation, J Polym Environ, 2017, 25, 359–369.

- M. Ait Haki, M. Laabd, H. Chafai, H. Kabli, M. Ez-zahery, M. Bazzaoui, R. Lakhmiri, A. Albourine, Comparative adsorption of nitrate ions on the polypyrrole and polyaniline from aqueous solution, J Dispers Sci Technol, 2017, 38, 598–603.

- M. Laabd, A. El Jaouhari, M. Ait Haki, H. Eljazouli, M. Bazzaoui, H. Kabli, A. Albourine, Simultaneous removal of benzene polycarboxylic acids from water by polypyrrole composite filled with a cellulosic agricultural waste, J Environ Chem Eng, 2016, 4, 1869–1879.

- J. E. Efome, D. Rana, T. Matsuura, C. Q. Lan, Effects of operating parameters and coexisting ions on the efficiency of heavy metal ions removal by nano-fibrous metal-organic framework membrane filtration process, Sci Total Environ, 2019, 674, 355–362.

- V. K. Gupta, I. Ali, T. A. Saleh, M. N. Siddiqui, S. Agarwal, Chromium removal from water by activated carbon developed from waste rubber tires, Environ Sci Pollut Res, 2013, 20, 1261–1268.

- M. Ghaedi, S. Hajjati, Z. Mahmudi, I. Tyagi, S. Agarwal, A. Maity, V. K. Gupta, Modeling of competitive ultrasonic assisted removal of the dyes–Methylene blue and Safranin-O using Fe3O4 nanoparticles, Chem Eng J, 2015, 268, 28–37.

- M. Baziar, A. Azari, M. Karimaei, V. K. Gupta, S. Agarwal, K. Sharafi, M. Maroosi, N. Shariatifar, S. Dobaradaran, MWCNT-Fe3O4 as a superior adsorbent for microcystins LR removal: Investigation on the magnetic adsorption separation, artificial neural network modeling, and genetic algorithm optimization, J Mol Liq, 2017, 241, 102–113.

- A. Asfaram, M. Ghaedi, S. Agarwal, I. Tyagi, V. Kumar Gupta, Removal of basic dye Auramine-O by ZnS:Cu nanoparticles loaded on activated carbon: optimization of parameters using response surface methodology with central composite design, RSC Adv, 2015, 5, 18438–18450.

- M. Laabd, L. Atourki, H. Chafai, M. Bazzaoui, M. Elamine, A. Albourine, A combined experimental and DFT investigation of the adsorption of humic acid by-products on polypyrrole, J Dispers Sci Technol, 2017, 38, 1227–1233.

- H. Chafai, H. Lotfi, M. Bazzaoui, A. Albourine, Adsorption du salicylate de sodium et du Cr (VI) par le polypyrrole, J Mater Env Sci, 2013, 4, 285–292.

- M. Otero, C. A. Grande, A. E. Rodrigues, Adsorption of salicylic acid onto polymeric adsorbents and activated charcoal, React Funct Polym, 2004, 60, 203–213.

- M. Essandoh, B. Kunwar, C. U. Pittman, D. Mohan, T. Mlsna, Sorptive removal of salicylic acid and ibuprofen from aqueous solutions using pine wood fast pyrolysis biochar, Chem Eng J, 2015, 265, 219–227.

- X. Ling, H. Li, H. Zha, C. He, J. Huang, Polar-modified post-cross-linked polystyrene and its adsorption towards salicylic acid from aqueous solution, Chem Eng J, 2016, 286, 400–407.

- M. Laabd, A. Hallaoui, N. Aarb, A. Essekri, H. Eljazouli, R. Lakhmiri, A. Albourine, Removal of Polycarboxylic Benzoic Acids Using Polyaniline-polypyrrole Copolymer: Experimental and DFT Studies, Fibers Polym, 2019, 20, 896–905.

- M. A. Zazouli, A. Azari, S. Dehghan, R. Salmani Malekkolae, Adsorption of methylene blue from aqueous solution onto activated carbons developed from eucalyptus bark and Crataegus oxyacantha core, Water Sci Technol, 2016, 74, 2021–2035.

- M. Laabd, A. El Jaouhari, H. Chafai, M. Bazzaoui, H. Kabli, A. Albourine, Experimental and theoretical studies on the removal of polycarboxy-benzoic acids by adsorption onto polyaniline from aqueous solution, Desalination Water Treat, 2016, 57, 15176–15189.




DOI: http://dx.doi.org/10.13171/mjc02004181260aa

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