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Electrochromism and conductivity of sulfonated polyaniline films in propylene carbonate

Daiane Fossatti, Wilson Jose da Silva, Regina Maria Queiroz de Mello

Abstract


In this work we compare the spectroelectrochemical response of electrochemically deposited sulfonated polyaniline and polyaniline films. The electrochromic performance of SPAN is slightly superior to that of PANI, showing faster coloring and bleaching and slightly higher electrochromic efficiency than PANI. Furthermore, submitting SPAN to successive voltammetry scans in LiClO4/propylene carbonate constitutes a simple method to improve SPAN conductivity by a factor 20.

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- P.M.S. Monk, R.J. Mortimer, D.R. Rosseinsky, Electrochromism and electrochromic devices, 2007, Cambridge University Press, Cambridge.

- R.J. Mortimer, Chem Soc Rev, 1997, 26,147-156.

- M-C Bernard, A. Hugot-Le Goff, W. Zeng, Electrochim Acta 1998, 44,781-786.

- G. Di Marco, M. Lanza, A. Pennisi, F. Simone, Solid State Ionics,2000, 127,23-29.

- M.P. Cantão, J.I. Cisneros, R.M. Torresi, J Phys Chem, 1994, 98,4865-4869.

- R. Cinnsealach, G. Boschloo, S.N. Rao, D. Fitzmaurice, Sol Energy Mater Sol Cells , 1999, 57,107-125.

- P.R. Somani, S. Radhakrishnan, Mater Chem Phys , 2002, 77,117-133.

- J.J. Garcia-Jareño, C. Gabrielli, H. Perrot, Electrochem Commun , 2000, 2,195-200.

- B.P. Jelle, G. Hagen, Sol. Energy Mater Sol Cells , 1999, 58,277-286.

- R. J. Mortimer, Electrochim Acta , 1999, 44,2971-2981.

- M. Mastragostino, In: B. Scrosati Ed., Applications of electroactive polymers, Chapman & Hall, New York , 1993.

- P.M.S. Monk, R.J. Mortimer, D.R. Rosseinsky, Electrochromism: fundamentals and applications - VCH, Weinheim, 1995.

– M. Vidotti, S.I.C. de TORRESI. J Braz Chem Soc, 2008, 19, 1248-1257.

- M.A. De Paoli, W.A. Gazotti, J Braz Chem Soc , 2002, 13,410-424.

- A.A. Argun, P-H. Aubert, B.C. Thompson, I. Schwendeman, C.L. Gaupp, J. Hwang, Chem Mater , 2004, 16,4401-4412.

- J.C. Lacroix, K.K. Kanazawa, A. Diaz, J Electrochem Soc, 1989, 136, 1308-1313.

- M. Morita, J Polym Sci Part B: Polym Phys , 1994, 32, 231-242.

- H. Tsutsumi, S. Fukuzawa, M. Ishikawa, M. Morita, Y. Matsuda, Synth Met , 1995, 72, 231-235

- J. Yue, A.J. Epstein, J Am Chem Soc , 1990, 112, 2800

- J.Y. Bergeron, J-W. Chevalier, L.H. Dao, J Chem Soc Chem Commun , 1990, 180

- S. Jung, H. Kim, M. Ha, Y. Kang, E. Kim, Mater Sci Eng C , 2004, 24, 57

- M.C. Bernard, A. H-Le Goff, S. Joiret, H. Arkoub, B. Saïdani, Electrochim Acta , 2005, 50, 1615-1623.

- A. Malinauskas, J Power Sources , 2004, 126, 214-220.

- X.-L. Wei, Y. Z. Wang, S. M. Long, C. Bobeczko, A. J. Epstein, J Am Chem Soc, 1996, 118, 2545–2555

- C. Li, S. Mu, Synth Met , 2004, 144, 143-149

- J.Y. Lee, C.Q. Cui, X.H. Su, M.S. Zhou, J Eletroanal Chem , 1993, 360, 177-187

- C. Barbero, R. Kotz, Adv Mater , 1994, 6, 577-580.

- R.M.Q. Mello, J.P.M. Serbena, A.R.V. Benvenho, I.A. Hümmelgen, J Solid State Electrochem , 2003, 7, 463-467.

- R.M.Q. Mello, I.A. Hümmelgen, J Solid State Electrochem , 2001, 5, 546-549.

- J. Yue, Z.H. Wang, K.R. Cromack, A.J. Epstein, A.G. MacDiarmid, J Am Chem Soc , 1991, 113, 2665-2671.

- R. Maeikien , G. Niaura, A. Malinauskas, Synth Met , 2003, 139, 89-94

- Y. Xia, J.M. Wiesinger, A.G. MacDiarmid, A.J. Epstein, Chem Mater, 1995, 7, 443-445.

- H. Tsutsumi, S. Yamashita, T. Oishi, J Appl Electrochem, 1997, 27, 477-481.

- R.M.Q. Mello, R.M. Torresi, S.I.C. de Torresi, E.A. Ticianelli, Langmuir , 2000, 16, 7835-7841.

- D.E. Stilwell, S-M. Park, J Electrochem Soc, 1989, 136, 427-433.

- C.Nguyen van Huong, M.J. Gonzalez-Tejera, J Electroanal Chem, 1990, 295, 357-371.

- C. Marcel, J.-M. Tarascon, Solid State Ionics , 2001, 143, 89-101.

- L-M. Huang, C-H. Chen, T.-Chin Wen., A. Gopalan, Electrochim Acta , 2006, 51, 2756-2764.

- W.-S. Huang, B.D. Humphrey, A.G. MacDiarmid, J Chem Soc, Faraday Trans I , 1986, 82, 2385-2400.

- D. Cummins, G. Boschloo, M. Ryan, D. Corr, S.N. Rao, D. Fitzmaurice, J Phys Chem B, 2000, 104, 11449-11459.




DOI: http://dx.doi.org/10.13171/mjc.1.4.2011.29.12.16

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