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Coriandrum Sativum seeds as a green low-cost biosorbent for methylene blue dye removal from aqueous solution: spectroscopic, kinetic and thermodynamic studies

Lamya Kadiri, Abdelkarim Ouass, Youness Essaadaoui, El Housseine Rifi, Ahmed Lebkiri


Coriandrum sativum seeds (CSS) were investigated as a new eco-friendly and economic biosorbent for the removal of methylene blue (MB) dye from synthetic solutions. First, the spectroscopic analyses were effectuated using FTIR and SEM to confirm the possibility of CSS to remove MB dye from aqueous solutions. The study of the influence of different parameters, such as contact time, CSS mass, solution pH, MB concentration, and temperature was realized and proved the rapid and efficient power adopted by CSS as a removal of the studied dye. Also, the regeneration study was effectuated for four cycles with excellent adsorption rates. The modeling studies revealed that the studied process obeys the pseudo-second-order model and Langmuir isotherm model. The adsorption amount was found to be 107.53 mg/g. Finally, the determination of thermodynamic parameters indicated the exothermic and spontaneous type of the removal process of MB onto CSS.

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- L. Travieso, R. O. Canizares, R. Borja, F. Benitez, A. R. Dominguez, and V. Valiente, Heavy metal removal by microalgae, Bulletin of Environmental Contamination and Toxicology, 1999, 62, 144-151.

- A. Reife, A. Reife, H. S. Freeman, Environmental Chemistry Dyes and Pigments. John Wiley & Sons. 1996.

- S. S. Salih, T. K. Ghosh, Adsorption of Zn (II) ions by chitosan coated diatomaceous earth." International journal of biological macromolecules, 2018, 106, 602-610.

- S. S. Salih, T. K. Ghosh, Preparation and characterization of bioadsorbent beads for chromium and zinc ions adsorption." Cogent Environmental Science, 2017, 3, 1401577.

- S. S. Salih, T. K. Ghosh, Highly efficient competitive removal of Pb (II) and Ni (II) by chitosan/diatomaceous earth composite. Journal of environmental chemical engineering, 2018, 6, 435-443.

- S. S. Salih, T. K. Ghosh, Preparation and Characterization of Chitosan-Coated Diatomaceous Earth for Hexavalent Chromium Removal. Environmental Processes, 2018, 5, 23-39.

- E. Daneshvar, A. Vazirzadeh, A. Niazi, M. Sillanpää, and A. Bhatnagar, A comparative study of methylene blue biosorption using different modified brown, red and green macroalgae – Effect of pretreatment, Chemical Engineering Journal, 2017, 307, 435–446.

- E. çAğLar, Y. O. Donar, A. Sinağ, İ. Biroğul, S. Bilge, K. Aydincak, O. Pliekhov, Adsorption of anionic and cationic dyes on biochars, produced by hydrothermal carbonization of waste biomass: effect of surface functionalization and ionic strength,” Turkish Journal of Chemistry, 2018, 42, 86–99

- S. Zhang, Z. Wang, Y. Zhang, H. Pan, and L. Tao, Adsorption of Methylene Blue on Organosolv Lignin from Rice Straw, Procedia Environmental Science, 2016, 31, 3-11.

- S. Shakoor and A. Nasar, Adsorptive treatment of hazardous methylene blue dye from artificially contaminated water using cucumis sativus peel waste as a low-cost adsorbent, Groundwater for Sustainable Development, 2017, 5, 152-159.

- S. Rangabhashiyam, S. Lata, P. Balasubramanian, Biosorption characteristics of methylene blue and malachite green from simulated wastewater onto Carica papaya wood biosorbent, Surfaces and Interfaces, 2018, 10, 197-215.

- A. Aarfane, A. Salhi, M. El Krati, S. Tahiri, M. Monkade, E. K. Lhadi, M. Bensitel, Kinetic and thermodynamic study of the adsorption of Red195 and Methylene blue dyes on fly ash and bottom ash in aqueous medium, Journal of Material and Environmental Sciences, 2014, 5, 1927-1939.

- F. Sakr, A. Sennaoui, M. Elouardi, M. Tamimi, A. Assabbane, Adsorption study of Methylene Blue on biomaterial using cactus, Journal of Material and Environmental Sciences , 2015, 6, 397-406.

- A. Sarimeseli, Microwave drying characteristics of coriander (Coriandrum sativum L.) leaves, Energy Conversion and Management, 2011, 52, 1449-1453.

- K. Msaada, M. Ben Jemia, N. Salem, O. Bachrouch, J. Sriti, S. Tammar, I. Bettaieb, Antioxidant activity of methanolic extracts from three coriander (Coriandrum sativum L.) fruit varieties, Arabian Journal of Chemistry, 2013, 10, S3176-S3183.

- H. Wangensteen, A. B. Samuelsen, K. E. Malterud, Antioxidant activity in extracts from coriander, Food Chemistry, 2004, 88, 293-297.

- P. J. Delaquis, K. Stanich, B. Girard, G. Mazza, Antimicrobial activity of individual and mixed fractions of dill, cilantro, coriander and eucalyptus essential oils, International Journal of Food and Microbiology. 2002, 74, 101-109.

- S. Mandal, M. Mandal, Coriander (Coriandrum sativum L.) essential oil: Chemistry and biological activity, Asian Pacific Journal of Tropical Biomedicine 2015, 5, 421-428.

- V. Chithra, S. Leelamma, Coriandrum Sativum-mechanism of hypoglycemic action, Food Chemistry. 1999, 67, 229-231.

- L. Kadiri, M. Galai, M. Ouakki, Y. Essaadaoui, A. Ouass, M. Cherkaoui, E. H. Rifi, A. Lebkiri, Coriandrum Sativum.L Seeds Extract as a Novel Green Corrosion Inhibitor for Mild Steel in 1.0 M Hydrochloric and 0.5 M Sulfuric Solutions, Analytical and Bioanalytical Chemistry, 2018, 10, 249-268.

- L. Kadiri, A. Lebkiri, E. H. Rifi, A. Ouass, Y. Essaadaoui, I. Lebkiri, H. Hamad, Kinetic studies of adsorption of Cu (II) from aqueous

solution by coriander seeds (Coriandrum Sativum), E3S Web of conferences. 2018, 37, 02005.

- L. Kadiri, A. Lebkiri, E. H. Rifi, A. Ouass, Y. Essaadaoui, I. Lebkiri, H. Hamad, Characterization of coriander seeds Coriandrum Sativum, International Journal of Sciences, Engineering and Research. 2017, 8, 2303-2308.

- A. Khodabandehloo, A. Rahbar-Kelishami, H. Shayesteh, Methylene blue removal using Salix babylonica (Weeping willow) leaves powder as a low-cost biosorbent in batch mode: Kinetic, equilibrium, and thermodynamic studies, Journal of Molecular Liquids, 2017, 244, 540-548.

- V. K. Gupta, A. Mittal, V. Gajbe, J. Mittal, Removal and Recovery of the Hazardous Azo Dye Acid Orange 7 through Adsorption over Waste Materials: Bottom Ash and De-Oiled Soya, Industrial & Engineering Chemistry Research, 2006, 45, 1446-1453.

- A. K. Nayak and A. Pal, Green and efficient biosorptive removal of methylene blue by Abelmoschus esculentus seed: Process optimization and multi-variate modeling, Journal of Environmental Management, 2017, 200, 145-159.

- F. Bouaziz, M. Koubaa, F. Kallel, F. Chaari, D. Driss, R. E. Ghorbel, S. E. Chaabouni, Efficiency of almond gum as a low-cost adsorbent for methylene blue dye removal from aqueous solutions, Industrial Crops and Products, 2015, 74, 903-911.

- Y. Essaadaoui, A. Lebkiri, E. H. Rifi, L. Kadiri, A. Ouass, Adsorption of cobalt from aqueous solutions onto Bark of Eucalyptus. Mediterr.J.Chem., 2018, 7(2), 145-155.

- J. Pang, F. Fu, Z. Ding, J. Lu, N. Li, B. Tang, Adsorption behaviors of methylene blue from aqueous solution on mesoporous birnessite, Journal of the Taiwan Institute of Chemical Engineers, 2017, 77, 168-176.

- A. Abdallah, A. Hijazi, M. Hamieh, M. Alameh, J. Toufaily, H. Rammal, Treatment of industrial wastewater using a natural and biodegradable adsorbent based on Eucalyptus, Journal of Material and Environmental Sciences. 2016, 5, 4036-4048.

- M. Basu, A. K. Guha, and L. Ray, Adsorption of Lead on Cucumber Peel, Journal of Cleaner Production, 2017, 151, 603–615.

- M. Basu, A. K. Guha, and L. Ray, Biosorptive removal of lead by lentil husk, Journal of Environmental Chemical Engineering, 2015, 3, 1088-1095.

- Y. Essaadaoui, A. Lebkiri, E. H. Rifi, L. Kadiri, A. Ouass, Adsorption of lead by modified Eucalyptus camaldulensis barks: equilibrium, kinetic and thermodynamic studies, Desalination and water treatment. 2018, 111, 267-277.

- K. Z. Elwakeel, A. M. Elgarahy, S. H. Mohammad, Use of beach bivalve shells located at Port Said coast (Egypt) as a green approach for methylene blue removal, Journal of Environmental Chemical Engineering. 2017, 5, 578-587.

- A. K. Agarwal, M. S. Kadu, kinetics study on the adsorption of Ni2+ ions onto fly ash, Journal of Chemical Technology and Metallurgy, 2015, 50, 601-605.

- I. Langmuir, The constitution and fundamental properties of solids and liquids. Part I. Solids, Journal of the American chemical society, 1917, 39, 1848-1906

- A. Ouass, I. Ismi, H. Elaidi, A. Lebkiri, M. Cherkaoui, E. H. Rifi, Mathematical Modeling Of The Adsorption Of Trivalent Chromium By The Sodium Polyacrylate Beads, Journal of Material and Environmental Sciences, 2017, 8, 3448-3456.

- B. Xu, Y. Zhu, H. Liu, Z. Jin, T. Chen, The kinetic and thermodynamic adsorption of Eu(III) on synthetic maghemite, Journal of Molecular Liquids, 2016, 221, 171-178.

- C. S. T. Araújo, I. L. S. Almeida, H. C. Rezende, S. M. L. O. Marcionilio, J. J. L. Léon, T. N. de Matos, Elucidation of mechanism involved in adsorption of Pb(II) onto lobeira fruit ( Solanum lycocarpum ) using Langmuir, Freundlich and Temkin isotherms, Microchemical Journal, 2018, 137, 348-354.

- T. Liu, Y. Li, Q. Du, J. Sun, Y. Jiao, G. Yang, Z. Wang, Y. Xia, W. Zhang, K. Wang, H. Zhu, D. Wu, Adsorption of methylene blue from aqueous solution by graphene. Colloids and Surfaces B: Biointerfaces, 2012, 90, 197-203.

- P. Joshi, S. Manocha, Kinetic and thermodynamic studies of the adsorption of copper ions on hydroxyapatite nanoparticles, Materials Today: Proceedings. 2017, 4, 10455-10459.

- X. Liu, D.-J. Lee, Thermodynamic parameters for adsorption equilibrium of heavy metals and dyes from wastewaters, Bioresource Technol. 2014, 160, 24-31.

- A. Ouass, L. Kadiri, Y. Essaadaoui, R. A. Belakhmima, M. Cherkaoui, A. Lebkiri, E. H. Rifi, Removal of trivalent chromium ions from aqueous solutions by Sodium polyacrylate beads. Mediterr.J.Chem., 2018, 7(2), 125-134.

- C. C. Okoye, O. D. Onukwuli, C. F. Okey-Onyesolu, Utilization of salt activated Raphia hookeri seeds as biosorbent for Erythrosine B dye removal: Kinetics and thermodynamics studies, Journal of King Saud University, 2018, DOI:


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