Cover Image

Mathematical modeling and thermodynamic study of copper (II) removal from aqueous solution by Coriandrum Sativum seeds

Lamya Kadiri, Ahmed Lebkiri, EL Housseine Rifi, Abdelkarim Ouass, Youness Essaadaoui, Imane Lebkiri

Abstract


Coriandrum Sativum seeds (CSS), were tested as a new eco-friendly adsorbent of copper ions from aqueous solutions. Hence, the effect of the most influencing experimental parameters such as initial concentration of Cu (II) and the temperature was studied upon the adsorption process in order to use its results in following studies. Lagergren pseudo-first-order, pseudo-second-order, and Intraparticle diffusion models were used to describe the biosorption kinetics. The adsorption process was also analyzed by Langmuir, Freundlich and Temkin models and the maximum monolayer biosorption capacity of CSS was found to be 33,5 mg. g−1 by using the Langmuir model. So as to investigate the thermodynamic properties of the adsorption process, the Gibbs free energy (ΔG°), enthalpy (ΔH°), and entropy (ΔS°) values in the temperature range of 25-55C° were also calculated in order to conclude the process characteristics. SEM and EDAX analysis were effectuated in order to study the surface morphology of CSS before and after the adsorption process.


Full Text:

PDF

References


- A. Ouass, Y. Essaadaoui, L. Kadiri, I. Lebkiri, C. Lafreme, M. Cherkaoui, A. Lebkiri, E. H. Rifi, Adsorption of Cr (III) from aqueous solution by two forms of a superabsorbant polymer: parametric study and effect of activation mode. In E3S Web of Conferences. EDP Sciences, 2018, 37, 02001.

- L. Travieso, R. O. Canizares, R. Borja, F. Benitez, A. R. Dominguez, and V. Valiente, Heavy metal removal by microalgae, Bulletin of Environmental Contamination and Toxicology, 1999, 62, 144-151.

- A. Ouass, I. Ismi, H. Elaidi, A. Lebkiri, M. Cherkaoui, E. H. Rifi, Mathematical Modeling of the Adsorption of Trivalent Chromium by The Sodium Polyacrylate Beads, Journal of Material and Environmental Sciences, 2017, 8, 3448-3456.

- S. Elanza, A. Lebkiri, S. Marzak, E. H. Rifi, M. Lebkiri, C. Satif, Removal of lead ions from aqueous solution by the sugarcane bagasse, Journal of Material and Environmental Sciences, 2014, 5(5), 1591-1598.

- H. Serencam, D. Ozdes, C. Duran, M. Tufekci, Biosorption properties of Morus alba L. for Cd (II) ions removal from aqueous solutions, Environ. Monit. Assess., 2013, 185, 7, 6003-6011.

- S. S. Salih and T. K. Ghosh, Preparation and Characterization of Chitosan-Coated Diatomaceous Earth for Hexavalent Chromium Removal, Environmental Processes, 2018, 5(1), 23-39.

- S. S. Salih and T. K. Ghosh, Highly efficient competitive removal of Pb (II) and Ni (II) by chitosan/diatomaceous earth composite. Journal of environmental chemical engineering, 2018, 6(1), 435-443.

- S. S. Salih and T. K. Ghosh, Preparation and characterization of bioadsorbent beads for chromium and zinc ions adsorption. Cogent Environmental Science, 2017, 3(1), 1401577.

- S. S. Salih and T. K. Ghosh (2018). Adsorption of Zn (II) ions by chitosan coated diatomaceous earth. International journal of biological macromolecules, 2018, 106, 602-610.

- M. Basu, A. K. Guha, and L. Ray, Biosorptive removal of lead by lentil husk, Journal of Environmental Chemical Engineering, 2015, 3, 1088-1095.

- N. Feng, X. Guo, S. Liang, Y. Zhu, J. Liu, Biosorption of heavy metals from aqueous solutions by chemically modified orange peel, Journal of Hazardous Material, 2011, 185, 1, 49-54.

- M. Basu, A. K. Guha, and L. Ray, Adsorption of Lead on Cucumber Peel, Journal of Cleaner Production, 2017, 151, 603-615.

- A. Verma, S. Kumar, S. Kumar, Biosorption of lead ions from the aqueous solution by Sargassum filipendula: Equilibrium and kinetic studies, Journal of Environmental Chemical Engineering, 2016, 4(4), 4587-4599.

- N. Jain, T. A. Johnson, A. Kumar, S. Mishra, N. Gupta, Biosorption of Cd(II) on jatropha fruit coat and seed coat, Environ. Monit. Assess., 2015, 187 (7), 411.

- A. Sarimeseli, Microwave drying characteristics of coriander (Coriandrum sativum L.) leaves, Energy Conversion and Management, 2011, 52, 1449-1453.

- M. K Shahwar, A.H. El-Ghorab, F.M. Anjum, M.S. Butt, S. Hussain, M. Nadeem, Characterization of Coriander (Coriandrum sativum L.) Seeds and Leaves: Volatile and Non-Volatile Extracts, Industrial Crops and Products, 2012, 15(4), 736-747.

- Z. Zeković, M. Kaplan, B. Pavlić, E. O. Olgun, J. Vladić, O. Canlı, S. Vidović, Chemical characterization of polyphenols and volatile fraction of coriander (Coriandrum sativum L.) extracts obtained by subcritical water extraction, Industrial Crops and Products, 2016, 87, 54-63.

- K. Ghedira, P. Goetz, Coriandrum sativum L.(Apiaceae): Coriandre. Phytothérapie, 2015, 13 (2), 130-134.

- B. Laribi, K. Kouki, M. M'Hamdi, T. Bettaieb, Coriander (Coriandrum sativum L.) and its bioactive constituents. Fitoterapia, 2015, 103, 9-26.

- K. Msaada, M. Ben Jemia, N. Salem, O. Bachrouch, J. Sriti, S. Tammar, I. Bettaieb, Antioxidant activity of methanolic extracts from three coriander (Coriandrum sativum L.) fruit varieties, Arabian Journal of Chemistry, 2013, 10, S3176-S3183.

- H. Wangensteen, A. B. Samuelsen, K. E. Malterud, Antioxidant activity in extracts from coriander, Food Chemistry, 2004, 88, 293-297.

- P. J. Delaquis, K. Stanich, B. Girard, G. Mazza, Antimicrobial activity of individual and mixed fractions of dill, cilantro, coriander and eucalyptus essential oils, International Journal of Food and Microbiology. 2002, 74, 101-109.

- S. Mandal, M. Mandal, Coriander (Coriandrum sativum L.) essential oil: Chemistry and biological activity, Asian Pacific Journal of Tropical Biomedicine 2015, 5, 421-428.

- V. Chithra, S. Leelamma, Coriandrum Sativum-mechanism of hypoglycemic action, Food Chemistry. 1999, 67, 229-231.

- L. Kadiri, M. Galai, M. Ouakki, Y. Essaadaoui, A. Ouass, M. Cherkaoui, E. H. Rifi, A. Lebkiri, Coriandrum Sativum.L Seeds Extract as a Novel Green Corrosion Inhibitor for Mild Steel in 1.0 M Hydrochloric and 0.5 M Sulfuric Solutions, Analytical and Bioanalytical Chemistry, 2018, 10, 249-268.

- L. Kadiri, A. Lebkiri, E. H. Rifi, A. Ouass, Y. Essaadaoui, I. Lebkiri, H. Hamad, Kinetic studies of adsorption of Cu (II) from aqueous solution by coriander seeds (Coriandrum Sativum), E3S Web of conferences. 2018, 37, 02005., doi: https://doi.org/10.1051/e3sconf/20183702005.

- L. Kadiri, A. Lebkiri, E. H. Rifi, A. Ouass, Y. Essaadaoui, I. Lebkiri, H. Hamad, Characterization of coriander seeds “Coriandrum Sativum”, International Journal of Sciences, Engineering and Research. 2017, 8, 2303-2308.

- Y. Essaadaoui, A. Lebkiri, E. H. Rifi, L. Kadiri, A. Ouass, Adsorption of lead by modified Eucalyptus camaldulensis barks: equilibrium, kinetic and thermodynamic studies, Desalination and water treatment. 2018, 111, 267-277.

- A. Ouass, L. Kadiri, Y. Essaadaoui, R. A. Belakhmima, M. Cherkaoui, A. Lebkiri, E. H. Rifi, Removal of trivalent chromium ions from aqueous solutions by Sodium polyacrylate beads. Mediterranean Journal of Chemistry, 2018, 7, 125-134.

- L. Kadiri, A. Ouass, Y. Essaadaoui, E. H. Rifi, A. Lebkiri, Coriandrum Sativum seeds as a green low-cost biosorbent for methylene blue dye removal from aqueous solution: spectroscopic, kinetic and thermodynamic studies. Mediterranean Journal of Chemistry, 2018, 7(3), 204-216.

- Y. Essaadaoui, A. Lebkiri, E. H. Rifi, L. Kadiri, A. Ouass, Adsorption of cobalt from aqueous solutions onto Bark of Eucalyptus. Mediterranean Journal of Chemistry, 2018, 7(2), 145-155.

- J. Pang, F. Fu, Z. Ding, J. Lu, N. Li, B. Tang, Adsorption behaviors of methylene blue from aqueous solution on mesoporous birnessite, Journal of the Taiwan Institute of Chemical Engineers, 2017, 77, 168-176.

- M. Matouq, N. Jildeh, M. Qtaishat, M.; Hindiyeh, M.Q. Al Syouf, The adsorption kinetics and modeling for heavy metals removal from wastewater by Moringa pods, Journal of Environmental Chemical Engineering., 2015, 3(2), 775-784.

- Y. Zhao, F. Liu, X. Qin, Adsorption of diclofenac onto goethite: Adsorption kinetics and effects of pH, Chemosphere, 2017, 180, 373-378.

- J. P. Simonin, On the comparison of pseudo-first order and pseudo-second order rate laws in the modeling of adsorption kinetics, Chemical Engineering Journal, 2016, 300, 254-263.

- A. E. Ofomaja, Intraparticle diffusion process for lead (II) biosorption onto mansonia wood sawdust, Bioresour. Technol., 2010, 101 (15), 5868-5876.

- I. Mobasherpour, E. Salahi, M. Ebrahimi, Thermodynamics and kinetics of adsorption of Cu(II) from aqueous solutions onto multi-walled carbon nanotubes, Journal of Saudi Chemical Society, 2014, 18 (6), 792-801.

- I. Langmuir, The constitution and fundamental properties of solids and liquids. Part I. Solids, Journal of the American chemical society, 1917, 39, 1848-1906.

- B. Xu, Y. Zhu, H. Liu, Z. Jin, T. Chen, The kinetic and thermodynamic adsorption of Eu(III) on synthetic maghemite, Journal of Molecular Liquids, 2016, 221, 171-178.

- C.S. Araújo, I.L. Almeida, H.C. Rezende, S.M. Marcionilio, J.J. Léon, T.N. de Matos, Elucidation of mechanism involved in adsorption of Pb(II) onto lobeira fruit ( Solanum lycocarpum ) using Langmuir, Freundlich and Temkin isotherms, Microchem. J., 2018, 137, 348-354.

- M. Cegłowski, G. Schroeder, Removal of heavy metal ions with the use of chelating polymers obtained by grafting pyridine–pyrazole ligands onto polymethylhydrosiloxane, Chemical Engineering Journal, 2015, 259, 885-893.

- S. S. Salih, Preparation and characterization of bioadsorbent beads for removing selected heavy metal ions from wastewater, PhD diss., 2018.

- S.Guiza, Biosorption of heavy metal from aqueous solution using cellulosic waste orange peel, Ecological Engineering, 2017, 99, 134-140.

- Z. Mohamed, A. Abdelkarim, K. Ziat, S. Mohamed, Adsorption of Cu (II) onto natural clay: Equilibrium and thermodynamic studies, system, 2016, 10, 11.

- K. K. Krishnani, X. Meng, C. Christodoulatos, V. M. Boddu, Biosorption mechanism of nine different heavy metals onto biomatrix from rice husk, Journal of Hazardous Materials, 2008, 153 (3), 1222-1234.

- A. B. Pérez-Marín, V. M. Zapata, J. F. Ortuno, M. Aguilar, J. Sáez, M. Lloréns, Removal of cadmium from aqueous solutions by adsorption onto orange waste, Journal of Hazardous Materials, 2007, 139 (1), 122-131.

- M. Basu, A. K Guha, L. Ray, Adsorption Behavior of Cadmium on Husk of Lentil, Process Saf. Environ. Prot., 2017, 106, 11-22.

- P. Pavasant, R. Apiratikul, V. Sungkhum, P. Suthiparinyanont, S. Wattanachira, T. F. Marhaba, Bioresour. Technol., 2006, 97 (18), 2321-2329.

- J. S. Chang, R. Law, C. C. Chang, Biosorption of lead, copper and cadmium by biomass of Pseudomonas aeruginosa PU21, Water Res., 1997, 31 (7), 1651-1658.

- M. Minamisawa, H. Minamisawa, S. Yoshida, N. Takai, Adsorption Behavior of Heavy Metals on Biomaterials, Journal of Agricultural and Food Chemistry, 2004, 52 (18), 5606-5611.

- S. Karabulut, A. Karabakan, A. Denizli, Y. Yürüm, Batch removal of copper (II) and zinc (II) from aqueous solutions with low-rank Turkish coals, Separation and Purification Technology, 2000, 18 (3), 177-184.

- R. Gündoğan, B. Acemioğlu, M. H. Alma, Copper (II) adsorption from aqueous solution by herbaceous peat, Journal of Colloid and Interface Science, 2004, 269 (2), 303-309.




DOI: http://dx.doi.org/10.13171/mjc7619012111lk

Copyright (c) 2019 Mediterranean Journal of Chemistry