Kinetic studies on the adsorption of phenol from aqueous solution by coffee husk activated carbon
DOI:
https://doi.org/10.13171/mjc10702007271480klvAbstract
The kinetics of phenol adsorption from aqueous solution on activated carbons (ACs) obtained from coffee husk by potassium Hydroxide (KOH) activation at 650 and 750oC have been studied in the range of 100-250 mg L-1 initial phenol concentrations and at the temperatures range of 10 – 40oC. Kinetic models for phenol adsorption were evaluated using pseudo-first-order, pseudo-second-order, and Elovich models. The adsorption mechanism was investigated using Reichenberg, Boyd, and Weber and Morris models. The adsorption on coffee husk activated carbon was found to be a fast or speedy process with the adsorption rate, k2qe, in the range of 0.130 to 0.977 min-1. The adsorption process was mainly physical and promoted by chemical sorption and controlled not only by intra-particle diffusion but also by pore diffusion throughout the entire adsorption period.References
- Y. Zhou, F. Gao, Y. Zhao, J. Lu, Study on the extraction kinetics of phenolic compounds from petroleum refinery waste lye, J. Saudi Chem. Soc., 2014, 18, 589-592.
- Z. Li, Y. Zhang, L. Wang, Y. Yao, J. Wu, Y. Sun, M. Tian, J. Liu, Phenolic resin modified by boron-silicon with high char yield, Polym. Test., 2019, 73, 208-213.
- A. Brink, C.M. Sheridan, K.G. Harding, A kinetic study of a mesophilic aerobic moving bed biofilm reactor (MBBR) treating paper and pulp mill effluents: The impact of phenols on biodegradation rates, J. Water Process. Eng., 2017, 19, 35-41.
- S. Han, J. Cui, L. Gan, X. Zhou, Effects of reaction conditions on the phenol liquefaction of peanut shells, Bioresources, 2019, 14,
-1914.
- C.O. Guimaraes, A.B. Franca, G.R.L. Samanamud, E.P. Baston, R.C.Z. Lofrano, C.C.A. Loures, L.L.R. Naves, F.L. Naves, Optimization of treating phenol from wastewater through the TiO2-catalyzed advanced oxidation process and response surface methodology, Environ. Monit. Assess., 2019, 191, 349.
- N. Mojoudi, N. Mirghaffari, M. Soleimani, H. Shariatmadari, C. Belver, J. Bedia, Phenol adsorption on high microporous activated carbons prepared from oily sludge: equilibrium, kinetic and thermodynamic studies, Sci. Rep., 2019, 9, 1-12.
- S.S. Salih, A. Mahdi, M. Kadhom, T.K. Ghosh, Competitive adsorption of As(III) and As(V) onto chitosan/diatomaceous earth adsorbent, J. Environ. Chem. Eng., 2019, 7(5), 103407.
- S.S. Salih, H.N Mohammed, G.H. Abdullah, M. Kadhom, T.K. Ghosh, Simultaneous removal of Cu(II), Cd(II), and industrial dye onto a composite chitosan biosorbent, J. Polym. Environ., 2020, 28, 354-365.
- F.F. Barbier, T.G. Chabikwa, M.U. Ahsan, S.E. Cook, R. Powell, M. Tanurdzic, C.A. Beveridge, A phenol/chloroform-free method to extract nucleic acids from recalcitrant, woody tropical species for gene expression and sequencing, Plant Methods, 2019, 15, 62.
- D. Villanueva-Bermejo, F. Zahran, D. Troconis, M. Villalva, G. Reglero, T. Fornari, Selective precipitation of phenolic compounds from Achillea millefolium L. extracts by supercritical anti-solvent technique, J. Supercrit. Fluid., 2017, 120, 52-58.
- N. Benosmane, B. Boutemeur, S.M. Hamdi, M. Hamdi, Removal of phenol from aqueous solution using polymer inclusion membrane based on a mixture of CTA and CA, Appl. Water Sci., 2018, 8, 17.
- T. Wang, Z.Y. Xu, L.G. Wu, B.R. Li, M.X. Chen, S.Y. Xue, Y.C. Zhu, J. Cai, Enhanced photocatalytic activity for degrading phenol in seawater by TiO2-based catalysts under weak light irradiation, RSC. Adv., 2017, 7,
-31929.
- M.C. Le, K. Le Van, N.H. Nguyen, Theoretical study on the adsorption of phenol on activated carbon using density functional theory, J. Mol. Model., 2013, 19, 4395-4402.
- N. Mojoudi, N. Mirghaffari, M. Soleimani, H. Shariatmadari, C. Belver, J. Bedia, Phenol adsorption on high microporous activated carbons prepared from oily sludge: equilibrium, kinetic and thermodynamic studies, Sci. Rep., 2019, 9, 19352.
- K.S. Ukanwa, K. Patchigolla, R. Sakrabani, E. Anthony, S. Mandavgane, A Review of Chemicals to Produce Activated Carbon from Agricultural Waste Biomass, Sustainability, 2019, 11, 6204.
- L.G.C. Villegas, N. Mashhadi, M. Chen, D. Mukherjee, K.E. Taylor, N. Biswas, A Short Review of Techniques for Phenol Removal from Wastewater, Curr. Pollut. Rep., 2016, 2, 157-167.
- S. Karthikeyan, B. Sivakumar, N. Sivakumar, Film and Pore Diffusion Modeling for Adsorption of Reactive Red 2 from Aqueous Solution on to Activated Carbon Prepared from Bio-Diesel Industrial Waste, J. Chem., 2010, 7, 138684.
- E. Yakub, S.E. Agarry, F. Omoruwou, C.N. Owabor, Comparative study of the batch adsorption kinetics and mass transfer in phenol-sand and phenol-clay adsorption systems, Particul. Sci. Technol., 2019, 1-11.
- Y. Hu, Y. Zhang, Y. Hu, C.Y. Chu, J. Lin, S. Gao, D. Lin, J. Lu, P. Xiang, T.H. Ko, Application of wasted oolong tea as a biosorbent for the adsorption of methylene blue, J. Chem., 2019. https://doi.org/10.1155/2019/4980965.
- E. Lorenc-Grabowska, P. Rutkowski, High adsorption capacity carbons from biomass and synthetic polymers for the removal of organic compounds from water, Water, Air, & Soil Pollution, 2014, 225, 2082.
- K. Le Van, T.T. Luong Thi, Activated carbon derived from rice husk by NaOH activation and its application in a supercapacitor, Prog. Nat. Sci-Mater., 2014, 24, 191-198.
- P.A. Webb, C. Orr, Analytical methods in fine particle technology, Norcross, Ga.: Micromeritics Instrument Corp, 1997.
- H.P. Boehm, Surface Oxides on Carbon and Their Analysis: A Critical Assessment, Carbon, 2012, 40, 145-149.
- American Public Health Association (APHA), Standard Methods for the Examination of Water and Wastewater, 19th ed., Washington DC, 1995.
- B.H. Hameed, D.K. Mahmoud, A.L. Ahmad, Sorption equilibrium and kinetics of basic dye from aqueous solution using banana stalk waste, J. Hazard Mater., 2008, 158, 499-506.
- S. Lagergren, Zur theorie der sogenannten adsorption geloster stoffe. Kungliga Svenska Vetenskapsakademiens, Handlingar, 1898, 24,
-39.
- V. Vadivelan, K. V. Kumar, Equilibrium, kinetics, mechanism, and process design for the sorption of methylene blue onto rice husk,
J. Colloid Interface Sci., 2005, 286, 90-100.
- W. Yassine, S. Zyade, S. Akazdam, A. Essadki, B. Gourich, D.B. Left, A study of olive mill wastewater removal by a biosorbent prepared by olive stones, Med. J. Chem., 2019, 8, 420-434.
- A. Srivastava, M. Singh, K. Karsauliya, D.P. Mondal, P. Khare, S. Singh, S.P. Singh, Effective elimination of endocrine disrupting bisphenol
A and S from drinking water using phenolic resin-based activated carbon fiber: Adsorption, thermodynamic and kinetic studies, Environ. Nanotechnol. Monit. Manage., 2020, 14, 100316.
- M. de la Luz-Asunción, V. Sánchez-Mendieta, A. L. Martínez-Hernández, V. M. Castaño, C. Velasco-Santos, Adsorption of Phenol from Aqueous Solutions by Carbon Nanomaterials of One and Two Dimensions: Kinetic and Equilibrium Studies, J. Nanomater., 2015. https://doi.org/10.1155/2015/405036.
- M. Gouamid, M.R. Ouahrani, M.B. Bensaci, Adsorption Equilibrium, kinetics, and thermodynamics of methylene blue from aqueous solutions using Date Palm Leaves, Energy Procedia, 2013, 36, 898-907.
- R.L. Tseng, K.T. Wu, F.C. Wu, R.S. Juang, Kinetic studies on the adsorption of phenol, 4-chlorophenol, and 2,4-dichlorophenol from water using activated carbons, J. Environ. Manage., 2010, 91, 2208-2214.
- K.P. Singh, A. Malik, S. Sinha, P. Ojha, Liquid-phase adsorption of phenols using activated carbons derived from agricultural waste material, J. Hazard. Mater., 2008, 150, 626-641.
- R.S. Juang, F.C. Wu, R.L. Tseng, Mechanism of Adsorption of Dyes and Phenols from Water Using Activated Carbons Prepared from Plum Kernels, J. Colloid. Interface Sci., 2000, 227, 347-444.
- M.S. Dabhade, M.B. Saidutta, D.V.R. Murthy, Adsorption of Phenol on Granular Activated Carbon from Nutrient Medium: Equilibrium and kinetic study, Int. J. Environ. Res., 2009, 3, 557-568.
- F.X. Chen, C.R. Zhou, G.P. Li, F.F. Peng, Thermodynamics and kinetics of glyphosate adsorption on resin D301, Arab. J. Chem., 2016, 9, S1665-S1669.
- Y. Liu, J. Chen, M. Chen, B. Zhang, D. Wu, Q. Cheng, Adsorption characteristics and mechanism of sewage 2 sludge-derived adsorbent for removing sulfonated methyl 3 phenol resin in wastewater, RSC Adv., 2015, 93, 76160-76169.
- T.S. Anirudhan, P.G. Radhakrishnan, Thermodynamics and kinetics of adsorption of Cu(II) from aqueous solutions onto a new cation exchanger derived from tamarind fruit shell, J. Chem. Thermodyn., 2008, 40, 702-709.
- M. Chairat, S. Rattanaphani, J.B. Bremner, V. Rattanaphani, Adsorption kinetic study of lac dyeing on cotton, Dyes Pigm., 2008, 76, 435-439.
- D. Mohan, K.P. Singh, Single- and multi-component adsorption of cadmium and zinc using activated carbon derived from bagasse-An agricultural waste, Water Res., 2002, 36, 2304-2318.
- D. Reichenberg, Properties of ion-exchange resins in relation to their structure. III. Kinetics of exchange, J. Am. Chem. Soc., 1953, 75, 589-597.
- G.E. Boyd, A.W. Adamson, L.S. Myers, The exchange adsorption of ions from aqueous solutions by organic zeolites. II. Kinetic, J. Am. Chem. Soc., 1947, 69, 2836-2848.
- W.J. Weber, J.C. Morriss, Kinetics of adsorption on carbon from solution, J. Sanit. Eng. Div., 1963, 89, 31-60.
- A.U. Itodo, F.W. Abdulrahman, L.G. Hassan, S.A. Maigandi, H.U. Itodo, Intraparticle diffusion and intraparticulate diffusivities of herbicide on derived activated carbon, Researcher, 2010, 2, 74-86.
- M. Ahmaruzzaman, D.K. Sharma, Adsorption of phenols from wastewater, J. Colloid Interface Sci., 2005, 287, 14-24.
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