Synthesis, characterization and application of Al-Ag/ZnO nano-photocatalyst for dye degradation in a new multi-layered cylindrical photoreactor
Abstract
A new Al-Ag/ZnO nano-photocatalyst has been synthesized by doping technique for degradation of Reactive Blue 19 (RB19) under UV irradiation. The photocatalytic activity of the fabricated nanocatalyst has been investigated in a newly invented multi-layered cylindrical reactor. The synthesized Al-Ag/ZnO has much more photocatalytic activity as compared to the ZnO and Ag/ZnO at similar operating conditions. It is found that the photocatalytic degradation using the synthesized nano-photocatalyst follows pseudo first order kinetic model. The electrical energy consumption using the synthesized nano-photocatalyst in this work is much lower than those of the other process alternatives.
Full Text:
PDFReferences
- A. Aleboyeh, M. E.Olya, H. Aleboyeh, 2008. Electrical energy determination for an azo dye decolorization and mineralization by UV/H2O2 advanced oxidation process. J. Chem. Eng. 137 (2008) 518–524.
- A.H. Gemeay, G.R. El-Ghrabawy , A.B. Zaki, 2007.Kinetics of the oxidative decolorization of Reactive Blue-19 by acidic bromate in homogeneous and heterogeneous media J. Dyes and Pigments 73 (2007) 90-97.
- Y. He, J.F. Gao, F.Q. Feng, C. Liu, Y.Z. Peng, S.Y. Wang, 2012.The comparative study on the rapid decolorization of azo, anthraquinone and triphenylmethane dyes by zero-valent iron. J. Chemical Engineering 179 (2012) 8– 18.
- S. Dutta, S.A. Parsons, C. Bhattacharjee, P. Jarvis, S. Datta, S. Bandyopadhyay, 2009.Kinetic study of adsorption and photo-decolorization of Reactive Red 198 on TiO2 surface. J. Chemical Engineering 155 (2009) 674–679. M.
- A. Pirkarami, M.E. Olya, N.Yousefi Limaee, 2013. Decolorization of azo dyes by photo electro adsorption process using polyaniline coated electrode. J. Progress in Organic Coatings 76 (2013) 682– 688
- S. Mohammadi-Aghdam, R. Marandi, M.E. Olya, A.A. Mehrdad Sharif, 2013. Kinetic modeling of BB41 photocatalytic treatment in a semibatch flow photoreactor using a nano composite film. J. Saudi Chemical Society 20 (2013) 103-109.
- R. Marandi, M.E. Olya, B. Vahid, M. Khosravi, , M. Hatami, Kinetic Modeling of Photocatalytic Degradation of an Azo Dye Using Nano-TiO2/Polyester. J. Environmental Engineering Science. 25 (2012) 108-119.
- C. Karunakaran, V. Rajeswari, P. Gomathisankar, 2011. Optical, electrical, photocatalytic, and bactericidal properties of microwave synthesized nanocrystalline AgeZnO and ZnO. J. Solid State Sciences 13 (2011) 923-928.
- C. Wanga, Z. Chen, Y. He, L. Li, D. Zhang, 2009. Structure, morphology and properties of Fe-doped ZnO films prepared by facing-target magnetron sputtering system. J. Applied Surface Science 255 (2009) 6881–6887.
- Y. Lou, S. Yuan, Y. Zhao, P. Hub, Z. Wanga, M. Zhang, L. Shi, D. Li, 2013. A simple route for decorating TiO2 nanoparticle over ZnO aggregates dye-sensitized solar cell. J. Chemical Engineering Journal 229 (2013) 190–196.
- J. Iqbala, T. Jana, M. Ismailb, N. Ahmada, A. Arifa, M. Khana, M. Adila Sami-ul-Haqa, A. Arshada, 2013 .Influence of Mg doping level on morphology, optical, electrical properties and antibacterial activity of ZnO nanostructures. J. Ceramics International in Press (2013)
- G. Li, X. Zhu, X. Tang, W. Song, Z. Yang, J. Dai, Y. Sun, X. Pan, S. Dai, 2011. Doping and annealing effects on ZnO:Cd thin films by sol–gel method. J.Alloys and Compounds 509 (2011) 4816–4823
- S. Ameen, M. Shaheer Akhtar, H. K.Seo, Y. Soon Kim, H. Shik Shin, 2012. Influence of Sn doping on ZnO nanostructures from nanoparticles to spindle shape and their photoelectrochemical properties for dye sensitized solar cells. J. Chem. Eng. 187 (2012) 351–356
- L. Arda, M. Acikgoz, Z.K. Heiba, N. Dogan, D. Akcan, O. Cakiroglue, 2013. Synthesis, characterization and ESR studies of powder Zn0.95−xMg0.05 AlxO (x=0, 0.01, 0.02, 0.05, and 0.1) nanocrystals. Solid State Comm. 170 (2013) 14–18
- W. Xie, Y. Li, W. Sun, J. Huang, H. Xie, X. Zhao, 2010. Surface modification of ZnO with Ag improves its photocatalytic efficiency and photostability, J. Photochemistry and Photobiology A: Chemistry. 216 (2010) 149–155.
- Y. Li, J. Meng, 2014. Al-doping effects on structure and optical properties of ZnO nanostructures. Materials Letters 117 (2014) 260–262.
- D. Fang, K. Lin, T. Xue, C. Cui, X. Chen, P. Yao, H. Li, 2014. Influence of Al doping on structural and optical properties of Mg–Al co-doped ZnO thin films prepared by sol–gel method. Journal of Alloys and Compounds 589 (2014) 346–352.
- C. Aydın, M.S. Abd El-sadek, K. Zheng, I.S. Yahia, F. Yakuphanoglu, 2013. Synthesis, diffused reflectance and electrical properties of nanocrystalline Fe-doped ZnO via sol–gel calcination technique. J. Optics & Laser Technology 48 (2013) 447–452.
- H. J.Son, K.A. Jeon, C.E. Kim, J.H. Kim, K.H. Yoo, S.Y. Lee, 2013. Synthesis of ZnO nanowires by pulsed laser deposition in furnace. Optics & Laser Technology 48 (2013) 447–452.
- Q. Simon, D. Barreca, D. Bekermann, A. Gasparotto, E.C. Maccato, V. Gombac, P. Fornasiero, O.I. Lebedev, S. Turner, A. Devi, R.A. Fischer, G.V. Tendeloo, 2011. Plasma-assisted synthesis of Ag/ZnO nanocomposites: First example of photo-induced H2 production and sensing. J. Hydrogen Energy 36 (2011) 15527–15537.
- S. Mitra, K. Sridharan, J. Unnam, K. Ghosh, 2008. Synthesis of nanometal oxides and nanometals using hot-wire and thermal CVD. J.Thin Solid Films 516 (2008) 798–802.
- A.A. Ismail, A. El-Midany, E.A. Abdel-Aal, H. El-Shall, 2005. Application of statistical design to optimize the preparation of ZnO nanoparticles via hydrothermal technique. J. Materials Letters 59 (2005) 1924–1928.
- Z. Chen, Y. Yanc, Microwave induced solution combustion synthesis of nano-sized phosphors. J. Alloys and Compounds 473 (2009) 13–16.
- V. Jeena, S.R. Ross, 2014. An environmentally friendly, cost effective synthesis of quinoxalines: the influence of microwave reaction conditions. J.Tetrahedron Letters 55 (2014) 642–645.
- M.H. Eman, A. Sobhi, A. Gomha, F. Thoraya, 2013. Multicomponent reactions for synthesis of bioactive polyheterocyclic ring systems under controlled microwave irradiation. Arabian Journal of Chemistry Available online 25 November 2013.
- M.N. Chong, B. Jin, C.W.K. Chow, C. Saint, 2010. Recent developments in photocatalytic water treatment technology: A review. J. water research 44 (2010) 2997-3027
- C. H. Wu, 2008. Effects of sonication on decolorization of C.I. Reactive Red 198 in UV/ZnO system. J. Hazardous Materials 153 (2008) 1254–1261
- B. Krishnakumar, M. Swaminathan, 2011. Influence of operational parameters on photocatalytic degradation of a genotoxic azo dye Acid Violet 7 in aqueous ZnO suspensions. J. Spectrochimica Acta Part A 81 (2011) 739– 744
- M. Ahmad, E. Ahmedb, Y. Zhang, N.R. Khalid, J. Xu, M. Ullah, Z. Hong, 2013. Preparation of highly efficient Al-doped ZnO photocatalyst by combustion synthesis. J. Current Applied Physics 13 (2013) 697-704.
- L. Wu, Y. Wu, 2005. Preparation of ZnO Nanorods and optical characterizations. J. Physica E: Low-dimensional Systems and Nanostructures 28 (2005) 76–82
- Y.J. Kwon, K.H. Kim, C.S. Lim, , 2002. Characterization of ZnO nanopowder synthesized by the polymerized complex method via an organochemical route. J. Ceram Proc Res, 3 (2002) 146-149.
- R.F. Silva, M.E.D. Zaniquelli, 2013. Morphology of nanometric size particulate aluminium-doped zinc oxide films. J. Colliod Surf Physicochem Eng Aspect, 198 (2013) 551-558.
- W. Tang, D.C. Cameron, 1996. Electroluminescent zinc sulphide devices produced by sol-gel processing . J. Thin Solid Films 280 (1996) 221.
- A. H.Shah, E. Manikandan, A. M.Basheer, V. Ganesan, 2013. Enhanced Bioactivity of Ag/ZnO Nanorods-A Comparative Antibacterial Study. J. Nanomed Nanotechol 4 (2013) 2-6.
- A.Ortiz, J.C. Alonso, V. Pankov, A. Huanosta, E. Andrade, 2000. Characterization of amorphous aluminum oxide films prepared by the pyrosol process Thin. J. Solid Films 368 (2000) 74.
- B. Divbanda, M. Khatamian, G.R. Kazemi Eslamian, M. Darbandi, 2013. Synthesis of Ag/ZnO nanostructures by different methods and investigation of their photocatalytic efficiency for 4-nitrophenol degradation. J. Applied Surface Science 284 (2013) 80– 86.
- A. Aprilia, P. Wulandari, R. Hidayat, A. Fujii, M. Ozaki, 2013. Influences of dopant concentration in sol–gel derived AZO layer on the performance of P3HT:PCBM based inverted solar cell. Solar Energy Materials & Solar Cells 111, 181 (2013)188.
- T. Hajizadegan, M. Jafari, M. Rashidzadeh, A. Saffar-Teluri, , 2013. A high activity adsorbent of ZnO–Al2O3 nanocomposite particles: Synthesis, characterization and dye removal efficiency. J. Applied Surface Science 276 (2013) 317–322
- G.L. PUMA, 2005. Dimensionless Analysis of Photocatalytic Reactors Using Suspended Solid Photocatalysts. J.Chemical Engineering Research and Design 83 (2005) 820–826
- N. Modirshahla, A. Hassani, M.A. Behnajady, R. Rahbarfam, 2011. Effect of operational parameters on decolorization of Acid Yellow 23 from wastewater by UV irradiation using ZnO and ZnO/SnO2 photocatalysts. J. Desalination. 271 (2011) 187–192.
- B. Gözmen, M. Turabik, A. Hesenov, 2009. Photocatalytic degradation of Basic Red 46 and Basic Yellow 28 in single and binary mixture by UV/TiO2/periodate system. J. Hazardous Materials. 164 (2009) 1487–95.
- C. E. Housecroft, S.A. Gharpe, 2004. Inorganic Chemistry (2nd ed.). Prentice Hall. pp. 173–4. (2004).
- M.M. Ba-Abbad, A.A.H. Kadhum, A.B. Mohammad, M.S. Takriff, K. Sopian, 2013. Visible light photocatalytic activity of Fe(3+)-doped ZnO nanoparticle prepared via sol-gel technique. J. Chemosphere. 91 (2013) 1604–11.
- P. Canizares, M. Hernandez-Ortega, M.A. Rodrigo, C.E. Barrera-Diaz, G. Roa-Morales, C. Saez, A comparison between Conductive-Diamond Electrochemical Oxidation and other Advanced Oxidation Processes for the treatment of synthetic melanoidins. J. Hazardous aterials 164 (2009) 120–125
- M.E. Olya, A. Pirkarami, M. Soleimani, M. Bahmaei, 2013. Photoelectrocatalytic degradation of acid dye using Ni-TiO2 with the energy supplied by solar cell: Mechanism and economical studies. J. Environmental Management 121 (2013) 210-219.
- J. Ulson, J. Alison, D.F. Ollis, 2006. Kinetics of dye decolorization in an air–solid system. J.Applied Catalysis B: Environmental 65 (2006) 315–325
- N. Helaıli, Y. Bessekhouad, A. Bouguelia, M.Trari, 2010. p-Cu2O/n-ZnO heterojunction applied to visible light Orange II degradation. J. Solar Energy 84 (2010) 1187–1192
- C. Lizama, J. Freer, J. Baeza, H.D. Mansilla, 2002. Optimized photodegradation of Reactive Blue 19 on TiO2 and ZnO suspensions. J.Catalysis Today 76 (2002) 235–246
- W.A. Sadik, 2007. Decolourization of an Azo Dye by Heterogeneous Photocatalysis. J.rocess Safety and Environmental Protection 85 (2007) 515–520
- Y. Bessekhouad, R. Brahimia, F. Hamdinia, M. Trari, 2012. Cu2S/TiO2 heterojunction applied to visible light Orange II degradation. J. Photochemistry and Photobiology A: Chemistry 248 (2012) 15– 23.
Refbacks
- There are currently no refbacks.
Copyright (c) 2015 Mediterranean Journal of Chemistry